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Platinum Group Metals

  • Platinum iridium alloy sheet
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Platinum Group Metals

Platinum group metals have similar physical and chemical properties as well as their own unique characteristics. For example: they are all in silvery white except osmium and ruthenium in steel gray, all of them have high melting point, high strength, thermal stability, high resistance to spark erosion, excellent corrosion resistance, strong oxidation resistance and good catalytic activity. At the meanwhile, different performances determine different uses. Platinum has good plasticity, stable resistance and resistance temperature coefficient. When it is forged into platinum wires and platinum foils, it will not be combined with oxygen, not be eroded by acid or alkali as well. It is only dissolved in hot aqua regia. Palladium can be dissolved in concentrated nitric acid and it can absorb 350 ~ 850 times the volume of hydrogen at room temperature. Rhodium and iridium insoluble in aqua regia can react with molten sodium hydroxide and sodium peroxide and produce compounds dissolved in acid. Osmium and ruthenium are not soluble in aqua regia, but they are easily oxidized to four oxides.

The Thermodynamic Properties of Platinum Group Metals
Platinum group metals Ru Rh Pd Os Ir Pt
Superconducting Temperature(Te)/K 0.48 0.000325 - 0.64 0.1125 -
Electron Specific Heat coefficient.(γ)/mJ·mol-1·K-2 3.00 4.65 9.42 2.05 3.20 6.54
Debye temperature(θD)/K 550 512 272 467 420 236
Thermodynamic Properties of Platinum Group Metals (gas phase) at 298.15K.
Platinum Group Metals Ru Rh Pd Os Ir Pt
Mole Specific Heat Capacity/J·mol-1·K-1 21.524 21.014 20.786 20.788 20.788 25.531
Enthalpy/J·mol-1 6235.2 6206.6 6197.4 6197.4 6197.4 6576.4
Entropy/J·mol-1·K-1 186.509 185.827 167.066 192.579 193.584 192.409
Thermodynamic Properties of Platinum Group Metals (solid phase) at 298.15K.
Platinum Group Metals Ru Rh Pd Os Ir Pt
Mole Specific Heat Capacity/J·mol-1·K-1 24.05 24.90 25.85 24.69 25.09 25.65
Enthalpy/J·mol-1 4577 4914 5444 4992 5266 5694
Entropy/J·mol-1·K-1 28.50 31.56 37.64 32.56 35.49 41.53
Sublimation Heat/KJ·mol-1 649 558 377 788 670 565
The Melting Properties of Platinum Group Metals
Platinum Group Metals Ru Rh Pd Os Ir Pt
Melting Point/K 2606 2236 1828.0 3400 2719 2041.3
Melting Heat/KJ·mol-1 39.0 27.3 16.6 70.0 41.3 21.3
Melting Entropy/J·mol-1·K-1 15.0 12.2 8.8 20.6 15.2 10.4
Melting Vapour Pressure/Pa 1.05 0.505 4.23 7.75 0.984 0.019

Effect of different alloying elements on the hardness of annealed platinum alloy

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